Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g., recognising geological provinces, studying geological processes) as well in archaeological (e.g., informing on past human migrations), palaeontological/ecological (e.g., investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g., validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa). The initial study targeted the northern parts of the Northern Territory and Queensland in Australia. The samples were taken from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 < 87Sr/86Sr < 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and gradients), large-scale (>100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a >500 km-long northwest-southeast trending low anomaly (87Sr/86Sr < 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, high 87Sr/86Sr values (> 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g., weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.

This Record contains new zircon and monazite U-Pb geochronological data obtained via Sensitive High-Resolution Ion Micro Probe (SHRIMP) from nine samples of volcanic, volcaniclastic and plutonic igneous rocks of the central Lachlan Orogen and the New England Orogen, New South Wales. These data were obtained during the reporting period July 2014-June 2015, under the auspices of the collaborative Geochronology Project between the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA), which is part of the National Collaboration Framework (NCF).

This report presents the results of an elemental and carbon and oxygen isotope chemostratigraphy study on three historic wells; Kidson-1, Willara-1 and Samphire Marsh-1, from the southern Canning Basin, Western Australia. The objective of this study was to correlate the Early to Middle Ordovician sections of the three wells to each other and to wells with existing elemental and carbonate carbon isotope chemostratigraphy data from the Broome Platform, Kidson and Willara sub-basins, and the recently drilled and fully cored stratigraphic Waukarlycarly 1 well from the Waukarlycarly Embayment.

A major concern for regulators and the public with geological storage of CO2 is the potential for the migration of CO2 via a leaky fault or well into potable groundwater supplies. Given sufficient CO2, an immediate effect on groundwater would be a decrease in pH which could lead to accelerated weathering, an increase in alkalinity, release of major and minor ions and heavy metals (particularly Pd, Ni and Cr) as well as CO2 mobilisation of trace organic contaminants. These scenarios potentially occur in a high CO2 leakage event, therefore detection of a small leak, although barely perceptible, could provide an important early warning for a subsequent and more substantial impact. Different approaches are required for the detection and quantification of these low level leaks and are the subject of this paper. A 3 year groundwater survey was recently completed in the Surat Basin, which provided comprehensive water and isotopic analysis of groundwaters together with their exsolved gases. The gases were analysed for composition, -13CCO2, -13CCH4 and -2HCH4. Methane is prevalent in the major Surat Basin aquifers (e.g. Mooga, Gubberamunda and Hutton sandstones) and is invariably associated with a bacterial (methanogenic) carbonate reduction source, evident from its isotopic signature ('13CCH4 ~ -70', '2HCH4 ~ -220'). In addition to methane and low levels of CO2, trace ethane is common. Two neighbouring wells, however, were quite different to the other 85 wells surveyed. Their exsolved gases contained comparatively high ethane, but also C1-C6 hydrocarbons in addition to methane. Methane isotope systematics were significantly different from other groundwater wells completed in the same formation. The -13C of the CO2 was similar to the surrounding groundwater wells, but the relative proportion of CO2 in the gas was significantly higher. Combined, these characteristics are consistent with hydrocarbon biodegradation. There was little difference in the groundwater chemistry for these wells compared to the regional baseline. The study provides a useful analogue study for detection, at various scales, of a leaky well associated with a geological storage site. Compositional and isotopic analysis of exsolved gases from groundwater samples could be used to demonstrate non-equilibrium conditions and intrusion of exogenic CO2. Abstract for the 2013 International Association of Hydrologist Congress, Perth

Australia has been, and continues to be, a leader in isotope geochronology and geochemistry. While new isotopic data is being produced with ever increasing pace and diversity, there is also a rich legacy of existing high-quality age and isotopic data, most of which have been dispersed across a multitude of journal papers, reports and theses. Where compilations of isotopic data exist, they tend to have been undertaken at variable geographic scale, with variable purpose, format, styles, levels of detail and completeness. Consequently, it has been difficult to visualise or interrogate the collective value of age and isotopic data at continental-scale. Age and isotopic patterns at continental scale can provide intriguing insights into the temporal and chemical evolution of the continent (Fraser et al, 2020). As national custodian of geoscience data, Geoscience Australia has addressed this challenge by developing an Isotopic Atlas of Australia, which currently (as of November 2020) consists of national-scale coverages of four widely-used age and isotopic data-types: 4008 U-Pb mineral ages from magmatic, metamorphic and sedimentary rocks 2651 Sm-Nd whole-rock analyses, primarily of granites and felsic volcanics 5696 Lu-Hf (136 samples) and 553 O-isotope (24 samples) analyses of zircon 1522 Pb-Pb analyses of ores and ore-related minerals These isotopic coverages are now freely available as web-services for use and download from the GA Portal. While there is more legacy data to be added, and a never-ending stream of new data constantly emerging, the provision of these national coverages with consistent classification and attribution provides a range of benefits: vastly reduces duplication of effort in compiling bespoke datasets for specific regions or use-cases data density is sufficient to reveal meaningful temporal and spatial patterns a guide to the existence and source of data in areas of interest, and of major data gaps to be addressed in future work facilitates production of thematic maps from subsets of data. For example, a magmatic age map, or K-Ar mica cooling age map sample metadata such as lithology and stratigraphic unit is associated with each isotopic result, allowing for further filtering, subsetting and interpretation. The Isotopic Atlas of Australia will continue to develop via the addition of both new and legacy data to existing coverages, and by the addition of new data coverages from a wider range of isotopic systems and a wider range of geological sample media (e.g. soil, regolith and groundwater).

Petroleum geochemical datasets and information are essential to government for evidence-based decision making on natural resources, and to the petroleum industry for de-risking exploration. Geoscience Australia’s newly built Data Discovery Portal (https://portal.ga.gov.au/) enables digital discoverability and accessibility to key petroleum geochemical datasets. The portal’s web map services and web feature services allow download and visualisation of geochemical data for source rocks and petroleum fluids, and deliver a petroleum systems framework for northern Australian basins. The Petroleum Source Rock Analytics Tool enables interrogation of source rock data within boreholes and field sites, and facilitates correlation of these elements of the petroleum system within and between basins. The Petroleum Systems Summary Assessment Tool assists the user to search and query components of the petroleum system(s) identified within a basin. The portal functionality includes customised data searches, and visualisation of data via interactive maps, graphs and geoscientific tools. Integration of the petroleum systems framework with the supporting geochemical data enables the Data Discovery Portal to unlock the value of these datasets by affording the user a one-stop access to interrogate the data. This allows greater efficiency and performance in evaluating the petroleum prospectivity of Australia’s sedimentary basins, facilitating and accelerating decision making around exploration investment to ensure Australia’s future resource wealth <b>Citation:</b> Edwards, D.S., MacFarlane, S.K., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S., Ray, J. and Raymond, O., 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

<div>A minor update to Version 1.0: Lu Hf and O isotope data structure and delivery.</div><div><br></div><div>Isotopic data from rocks and minerals have the potential to yield unique insights into the composition and evolution of the Earth's crust and mantle. Time-integrated records of crust and mantle differentiation (as preserved by the U-Pb, Sm-Nd and Lu-Hf isotopic systems, for example) are important in a wide range of geological applications, especially when successfully integrated with other geological, geophysical, and geochemical datasets. However, such integration requires (i) compilation of comprehensive isotopic data coverages, (ii) unification of datasets in a consistent structure to facilitate inter-comparison, and (iii) easy public accessibility of the compiled and unified datasets in spatial and tabular formats useful and useable by a broad range of industry, government and academic users. This constitutes a considerable challenge, because although a wealth of isotopic information has been collected from the Australian continent over the last 40 years, the published record is fragmentary, and derived from numerous and disparate sources. Unlocking and harnessing the collective value of isotopic datasets will enable more comprehensive and powerful interpretations, and significantly broaden their applicability to Earth evolution studies and mineral exploration.</div><div><br></div><div>As part of the Exploring for the Future (EFTF) program (https://www.ga.gov.au/eftf), we have designed a new database structure and web service system to store and deliver full Lu-Hf isotope and associated O-isotope datasets, spanning new data collected during research programs conducted by Geoscience Australia (GA), as well as compiled literature data. Our approach emphasises the links between isotopic measurements and their spatial, geological, and data provenance information in order to support the widest possible range of uses. In particular, we build and store comprehensive links to the original sources of isotopic data so that (i) users can easily track down additional context and interpretation of datasets, and (ii) generators of isotopic data are appropriately acknowledged for their contributions.</div><div><br></div><div>This system delivers complete datasets including (i) full analytical and derived data as published by the original author, (ii) additional, normalised derived data recalculated specifically to maximise inter-comparability of data from disparate sources, (iii) metadata related to the analytical setup, (iv) a broad range of sample information including sampling location, rock type, geological province and stratigraphic unit information, and (v) descriptions of (and links to) source publications. The data is delivered through the Geoscience Australia web portal (www.portal.ga.gov.au), and can also be accessed through any web portal capable of consuming Open Geospatial Consortium (OGC)-compliant web services, or any GIS system capable of consuming Web Map Services (WMS) or Web Feature Services (WFS).</div><div><br></div><div>Version 1.0 of this Record (Waltenberg et al., 2021) described the database system and web service tables, and featured normalised Lu-Hf data that utilised CHondritic Uniform Reservoir (CHUR) parameters from Blichert-Toft and Albarède (1997). It also presented full tabulated datasets compiled from the North Australian Craton as part of the initial EFTF (2016–2020) program, comprising 5974 individual analyses from 149 unique rock samples. This update (version 1.1) enacts minor changes to some field names within the web services tables to ensure consistency with other web services offered by GA, and for normalised Lu-Hf data, it applies the CHUR parameters of Bouvier et al. (2008) to the entire dataset. The digital datasets presented by Waltenberg et al. (2021) have also been supplemented by more recent analyses collected as part of GA projects in Queensland and New South Wales, in collaboration with the relevant State geological surveys. Version 1.1 does not include an updated tabular data release; the digital dataset available via the web portal now comprises 7630 individual analyses from 180 unique rock samples.</div>

<div>The Carrara Sub-basin, discovered in 2017 based on interpretation of 2D deep seismic surveys acquired by Geoscience Australia, is a large sedimentary depocentre in the South Nicholson region straddling the Northern Territory and Queensland. It was interpreted to contain up to 8 km of Paleoproterozoic to Cambrian rocks including stratigraphic equivalents to the Isa Superbasin, South Nicholson Group and Georgina Basin. In order to validate these stratigraphic interpretations and assess the resource prospectivity of the Carrara Sub-basin, the South Nicholson National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020 as a collaboration between the MinEx Cooperative Research Centre, Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 was drilled on the western flanks of the Carrara Sub-basin and reached a total depth of 1751&nbsp;m, intersecting ca. 630&nbsp;m of Cambrian Georgina Basin overlying ca. 1100&nbsp;m of Proterozoic carbonates, black shales and minor siliciclastics. More than 400 NDI Carrara&nbsp;1 physical samples were analysed as part of an extensive geochemical program, including Rock-Eval pyrolysis and compositional analyses of hydrocarbon shows, whose results and implications for energy prospectivity are summarised here.</div> This Abstract was submitted/presented to the 2022 Australian Organic Geochemistry Conference 27-29 November (https://events.csiro.au/Events/2022/October/5/Australian-Organic-Geochemistry-Conference)

<div>The Australian continent comprises a broad dichotomy of crustal settings; from the Archean–Proterozoic cratonic core in the centre and west, to the accretionary margin of the Tasmanides in the east. These continental blocks meet at the Tasman Line, where successive arc systems built the eastern third of Australia in ca. 250 Myrs. This interface represents one of Australia’s most fundamental crustal boundaries and is marked by the ca. 520–490 Ma Delamerian Orogen in south-eastern Australia. Despite its first-order crustal control on tectonism, magmatism, deformation, and mineral systems in the area, the Delamerian Orogen remains poorly understood. Here, we present new zircon Hf-O isotopic and trace element data on 32 samples across the south-east Tasman Line. This initial dataset, which will grow over the next 12 months as part of Geoscience Australia’s Exploring for the Future program, will be used to constrain the time-space crustal architecture and evolution of Australia’s south-eastern Precambrian cratonic margin. These first samples include Paleoarchean to Devonian felsic magmatic rocks from the eastern Gawler Craton, across the Delamerian Orogen, to the Central Lachlan Orogen, and show that the crust of south-east Australia has a significant pre-history, with crustal reworking a major feature across the region. Delamerian arc magmatism appears to have involved significant reworking of Australia’s south-eastern Precambrian margin, as recorded by sub-chondritic Hf-isotope data. Assuming a significant mantle-component in the initial arc magmas, contamination by the ancient overlying continental rocks, some as old as ca. 3250 Ma, resulted in less juvenile compositions. This observation suggests Australia’s south-eastern Gondwanan margin may have consisted of a west-dipping continental arc, rather than an offshore island arc. The ‘heavy’ supracrustal δ18O of magmatic rocks across the area since the Paleoproterozoic is testament to the long-lived terrestrial nature of this continental margin, and its influence on magmatism across >1 billion years of Earth history.&nbsp;</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

An Isotopic Atlas of Australia (Fraser et al., 2020) provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. This poster provides example maps produced from compiled data of multiple geochronology and isotopic tracer datasets from this Isotopic Atlas, now publicly available and downloadable via Geoscience Australia’s (GA) Exploring for the Future (EFTF) <a href="https://portal.ga.gov.au/persona/geochronology">Geochronology and Isotopes Data Portal</a> and Mineral Resources Tasmania’s <a href="https://www.mrt.tas.gov.au/mrt_maps/app/list/map">Listmap</a>. These datasets and maps unlock the collective value of several decades of geochronological and isotopic studies conducted across Australia. Compiled geochronology, which commenced with coverage of northern Australia (Jones et al., 2018), is now much more comprehensive across Victoria (Waltenberg et al., 2021) and Tasmania (Jones et al., in press), with New South Wales and South Australia updates well underway. Available data include: Sm–Nd model ages of magmatic rocks; Lu–Hf isotopes from zircon and associated O-isotope data; Pb–Pb isotopes from ore-related minerals such as galena and pyrite; Rb–Sr isotopes from soils; U–Pb ages of magmatic, metamorphic and sedimentary rocks; and K–Ar, Ar–Ar, Re–Os, Rb–Sr and fission-track ages from minerals and whole rocks. <b>To view the associated poster see <a href="https://dx.doi.org/10.26186/147420">eCat 147420</a>. This Abstract & Poster were presented to the 2022 Specialist Group in Tectonics & Structural Geology(SGTSG) Conference 22-24 November (https://www.sgtsg.org/). </b> <i>Fraser, G.L., Waltenberg, K., Jones, S.L., Champion, D.C., Huston, D.L., Lewis, C.J., Bodorkos, S., Forster, M., Vasegh, D., Ware, B., Tessalina, S. 2020. An Isotopic Atlas of Australia. Geoscience Australia, Canberra. https://doi.org/10.11636/133772. Geoscience Australia. 2021. Geoscience Australia Exploring for the Future portal, viewed 13 September 2022. https://portal.ga.gov.au/persona/geochronology. Jones, S.L., Anderson, J.R., Fraser, G.L., Lewis, C.J., McLennan, S.M. 2018. A U-Pb Geochronology Compilation for Northern Australia: Version 2, 2018. Geoscience Australia Record 2018/49. https://doi.org/10.11636/Record.2018.049. Jones, S.L., Waltenberg, K., Ramesh, R., Cumming, G., Everard, J.L., Vicary, M.J., Bottrill, R.S., Knight, K., McNeill, A.W., Bodorkos, S., Meffre, S. in press. Isotopic Atlas of Australia: Geochronology compilation for Tasmania Version 1.0. Geoscience Australia Record. Mineral Resources Tasmania. 2022. Mineral Resources Tasmania Listmap, viewed 19 September 2022. https://www.mrt.tas.gov.au/mrt_maps/app/list/map. Waltenberg, K., Jones, S.L., Duncan, R.J., Waugh, S., Lane, J. 2021. Isotopic Atlas of Australia: Geochronology compilation for Victoria Version 1.0. Geoscience Australia Record 2021/24. https://doi.org/10.11636/Record.2021.024. </i>